Mixed Oxide (MOX) Fuel
(Updated May 2013)
- Mixed oxide (MOX) fuel provides about 2% of the new nuclear fuel used today.
- MOX fuel is manufactured from plutonium recovered from used reactor fuel.
- MOX fuel also provides a means of burning weapons-grade plutonium (from military sources) to produce electricity.
In every nuclear reactor there is both fission of isotopes such as uranium-235, and the formation of new, heavier isotopes due to neutron capture, primarily by U-238. Most of the fuel mass in a reactor is U-238. This can become plutonium-239 and by successive neutron capture Pu-240, Pu-241 and Pu-242 as well as other transuranic isotopes (see page on Plutonium). Pu-239 and Pu-241 are fissile, like U-235. (Very small quantities of Pu-236 and Pu-238 are formed similarly from U-235.)
Normally, with the fuel being changed every three years or so, about half of the Pu-239 is 'burned' in the reactor, providing about one third of the total energy. It behaves like U-235 and its fission releases a similar amount of energy. The higher the burn-up, the less fissile plutonium remains in the used fuel. Typically about one percent of the used fuel discharged from a reactor is plutonium, and some two thirds of this is fissile (c. 50% Pu-239, 15% Pu-241). Worldwide, some 70 tonnes of plutonium contained in used fuel is removed when refuelling reactors each year.
The plutonium (and uranium) in used fuel can be recovered through reprocessing. The plutonium could then be used in the manufacture mixed oxide (MOX) nuclear fuel, to provide energy through electricity generation. A single recycle of plutonium in the form of MOX fuel increases the energy derived from the original uranium by some 12%, and if the uranium is also recycled this becomes about 22% (based on light water reactor fuel with burn-up of 45 GWd/tU).
Today there is a significant amount of separated uranium and plutonium which may be recycled, including from ex-military sources. It is equivalent to about three years' supply of natural uranium from world mines.
Inventory of separated recyclable materials 1
||Natural U equivalent (tonnes)
|Plutonium from reprocessed fuel
|Uranium from reprocessed fuel
|Ex-military high-enriched uranium
In addition, there is about 1.6 million tonnes of enrichment tails, with recoverable fissile uranium.
MOX fuel was first used in a thermal reactor in 1963, but did not come into commercial use until the 1980s. So far about 2000 tonnes of MOX fuel has been fabricated and loaded into power reactors. In 2006 about 180 tonnes of MOX fuel was loaded into over 30 reactors (mostly PWR) in Europe.
Today MOX is widely used in Europe and in Japan. Currently about 40 reactors in Europe (Belgium, Switzerland, Germany and France) are licensed to use MOX, and over 30 are doing so. In Japan about ten reactors are licensed to use it and several do so. These reactors generally use MOX fuel as about one third of their core, but some will accept up to 50% MOX assemblies. France aims to have all its 900 MWe series of reactors running with at least one third MOX. Japan also plans to use MOX in one third of its reactors in the near future and expects to start up a 1383 MWe (gross) reactor with a complete fuel loading of MOX at the Ohma plant in late 2014.2 Other advanced light water reactors such as the EPR or AP1000 are able to accept complete fuel loadings of MOX if required.
In the USA there was significant development work in 1960s and 19790s, and MOX fuel was used in several demonstration projects (San Onofre, Ginna PWRs, Dresden, Quad Cities and Big Rock Point). It performed acceptably and similar to uranium oxide fuel. In 2005 four MOX test assemblies made by Melox in France were tested successfully at the Catawba power station.
The use of up to 50% of MOX does not change the operating characteristics of a reactor, though the plant must be designed or adapted slightly to take it. More control rods are needed. For more than 50% MOX loading, significant changes are necessary and a reactor needs to be designed accordingly, as several new designs are. Burn-up of MOX fuel is about the same as that for UOX fuel.
An advantage of MOX is that the fissile concentration of the fuel can be increased easily by adding a bit more plutonium, whereas enriching uranium to higher levels of U-235 is relatively expensive. As reactor operators seek to burn fuel harder and longer, increasing burnup from around 30,000 MW days per tonne a few years ago to over 50,000 MWd/t now, MOX use becomes more attractive.
Reprocessing to separate plutonium for recycle as MOX becomes more economic as uranium prices rise. MOX use also becomes more attractive as the need to reduce the volume of spent fuel increase. Seven UO2 fuel assemblies give rise to one MOX assembly plus some vitrified high-level waste, resulting in only about 35% of the volume, mass and cost of disposal.
Recycling normal used fuel
If used fuel is to be recycled, the first step is separating the plutonium and the remaining uranium (about 96% of the spent fuel) from the fission products with other wastes (together about 3%). The plutonium then needs to be separated from most or all of the uranium. All this is undertaken at a reprocessing plant (see information page on Processing of Used Nuclear Fuel).
The plutonium, as an oxide, is then mixed with depleted uranium left over from an enrichment plant to form fresh mixed oxide fuel (MOX, which is UO2+PuO2). MOX fuel, consisting of about 7-10% plutonium mixed with depleted uranium, is equivalent to uranium oxide fuel enriched to about 4.5% U-235, assuming that the plutonium has about two thirds fissile isotopes. If weapons plutonium is used (>90% Pu-239), only about 5% plutonium is needed in the mix. The plutonium content of commercial MOX fuel varies up to 10.8% depending on the design of the fuel, and averages about 9.5%. Fuel in an EPR with 30% MOX having less than 10.8% Pu is equivalent to 4.2% enriched uranium fuel. An EPR with 100% MOX fuel can use a wider variety of used fuel material (burnup, initial enrichment, Pu quality) than with only 30% MOX.
Plutonium from reprocessed fuel is usually fabricated into MOX as soon as possible to avoid problems with the decay of short-lived plutonium isotopes. In particular, Pu-241 (half-life 14 years) decays to Am-241 which is a strong gamma emitter, giving rise to a potential occupational health hazard if separated plutonium over five years old is used in a normal MOX plant. The Am-241 level in stored plutonium increases about 0.5% per year, with corresponding decrease in fissile value of the plutonium. Pu-238 (half-life 88 years), a strong alpha emitter and a source of spontaneous neutrons, is increased in high-burnup fuel. Pu-239, Pu-240 and Pu-242 are long-lived and hence little changed with prolonged storage. (See also information page on Plutonium).
Fast neutron reactors allow multiple recycling of plutonium, since all transuranic isotopes there are fissionable, but in thermal reactors isotopic degradation limits the plutonium recycle potential and most spent MOX fuel is stored pending the greater deployment of fast reactors. (The plutonium isotopic composition of used MOX fuel at 45 GWd/tU burnup is about 37% Pu-239, 32% Pu-240, 16% Pu-241, 12% Pu-242 and 4% Pu-238.)
Recovered uranium from a reprocessing plant may be re-enriched on its own for use as fresh fuel. Because it contains some neutron-absorbing U-234 and U-236, reprocessed uranium must be enriched significantly (e.g. one-tenth) more than is required for natural uranium. Thus reprocessed uranium from low-burn-up fuel is more likely to be suitable for re-enrichment, while that from high burn-up fuel is best used for blending or MOX fabrication.
Reprocessing of 850 tonnes of French used fuel per year (about 15 years after discharge) produces 8.5 tonnes of plutonium (immediately recycled as 100 tonnes of MOX) and 810 tonnes of reprocessed uranium (RepU). Of this about two-thirds is converted into stable oxide form for storage. One-third of the RepU is re-enriched and EdF has demonstrated its use in 900 MWe power reactors.
Two plants currently produce commercial quantities of MOX fuel – in France and UK. In 2006 a 40 t/yr Belgian plant closed3 and in April 2007 the French Melox plant was licensed for an increase in production from 145 to 195 t/yr. Also the Sellafield MOX Plant in UK was downrated from 128 to 40 t/yr, and in August 2011 the Nuclear Decommissioning Authority announced that it had reassessed the plant's prospects and would close it.
Japan is planning to start up a 130 t/yr J-MOX plant at Rokkasho in 2015. Meanwhile, construction on a MOX fabrication facility at the Savannah River Site in the USA is underway for 2016 start-up – see section below on MOX and disposition of weapons plutonium.
World mixed oxide fuel fabrication capacities (t/yr)
|Russia, Mayak, Ozersk
| Russia, Zheleznogorsk
|Total for LWR
MOX is also used in fast neutron reactors in several countries, particularly France and Russia. It was first developed for this purpose, with experimental work being done in USA, Russia, UK, France, Germany, Belgium and Japan. Today, Russia leads the way in fast reactor development and has long-term plans to build a new generation of fast reactors fuelled by MOX. The world's largest fast reactor – the 800 MWe BN-800 – is currently under construction at Beloyarsk in the Urals and due to start up in 2014.
At present the output of reprocessing plants exceeds the rate of plutonium usage in MOX, resulting in inventories of (civil) plutonium in several countries. These stocks are expected to exceed 250 tonnes before they start to decline after 2010 as MOX use increases, with MOX then expected to supply about 5% of world reactor fuel requirements.
The UK is investigating the incorporation of its 120 tonnes of reactor-grade plutonium into CANMOX fuel which would be used in four Candu EC6 reactors. The fuel would have 2% plutonium and four UK units (2800 MWe) would require about 400 t/yr of it. The used fuel would be stored for a hundred years and then sent to a repository.
MOX and disposition of weapons plutonium
Under the Plutonium Management and Disposition Agreement, Russia and the USA agreed in 2000 to each dispose of (or immobilise) 34 tonnes of weapons-grade plutonium deemed surplus to requirements (see page on Military Warheads as a Source of Nuclear Fuel).
The Mixed Oxide Fuel Fabrication Facility (MFFF) at the Savannah River Site in South Carolina began construction in August 2007 and will convert the US plutonium to MOX fuel. Expected to begin operations in 2016, the MFFF is designed to turn 3.5 t/yr of weapons-grade plutonium into about 150 MOX fuel assemblies, both PWR and BWR. The contract to design, build and operate the MFFF was awarded to the Shaw AREVA MOX Services consortium in 1999, with the $2.7 billion construction option being exercised in May 2008.4 Four MOX fuel lead test assemblies manufactured from US weapons plutonium and fabricated at the Melox plant in France were successfully burned on a trial basis at the Catawba plant.
Meanwhile, following several years of dispute, in November 2007 the USA and Russia agreed that Russia would dispose of its 34 t of weapons-grade plutonium by conversion to MOX fuel, which would be burned in the BN-600 reactor at the Beloyarsk nuclear plant, and in the BN-800 under construction at the same site.5 Under this plan, Russia would begin disposition in the BN-600 reactor in the 2012 timeframe. Disposition in the BN-800 would follow soon thereafter. Once disposition begins, the two reactors could dispose of approximately 1.5 t of Russian weapons plutonium per year. The USA agreed to contribute $400 million to the project. A 60 t/yr commercial MOX Fuel Fabrication Facility (MFFF) is scheduled to start up at Zheleznogorsk by 2014, operated by the Mining & Chemical Combine (MCC). It will make MOX granules and pelletised MOX for 400 fuel assemblies per year for the BN-800 and future fast reactors. The capacity is designed to supply five BN-800 units. This is likely to use ex-weapons plutonium. Another MOX plant for military plutonium was planned for Seversk, Siberia, but this appears to have been displaced by the MCC one.
MOX reprocessing and further use
Used MOX fuel reprocessing has been demonstrated since 1992 in France, at the La Hague plant. In 2004 the first reprocessing of used MOX fuel was undertaken on a larger scale with continuous process. Ten tonnes of MOX irradiated to about 35,000 MWd/t and with Pu content of about 4% was involved. The main problem of fully dissolving PuO2 was overcome. Since 2004 an increasing amount of MOX from German and Swiss reactors has been reprocessed, totaling about 70 tonnes, with a wide range of composition. As MOX is repeatedly recycled it is mixed with substantial proportions (70-80%) of plutonium from UOX fuel.
At present the French policy is not to reprocess used MOX fuel, but to store it and await the advent of fuel cycle developments related to Generation IV fast neutron reactor designs.
Since the early 1990s Russia has had a programme to develop a thorium-uranium fuel, which more recently has moved to have a particular emphasis on utilisation of weapons-grade plutonium in a thorium-plutonium fuel. The programme is described in the information page on Thorium. With an estimated 150 tonnes of surplus weapons plutonium in Russia, the thorium-plutonium project would not necessarily cut across existing plans to make MOX fuel.
1. OECD/NEA 2007, Management of Recyclable Fissile and Fertile Materials, NEA #6107 (ISBN: 9789264032552). [Back]
2. J-Power reschedules Ohma start-up, World Nuclear News, 11 November 2008. [Back]
3. Belgonucleaire's decision to close its MOX plant was explained in its 2005 Annual Report – see http://www.belgonucleaire.be/files/JAARVERSLAG2005EN.pdf [Back]
4. Final contract for US MOX, World Nuclear News, 27 May 2008. [Back]
5. Russia and USA confirm plutonium plan, World Nuclear News, 20 November 2007. [Back]
Australian Safeguards and Non-Proliferation Office, Annual Report 1999
NATO 1994, Managing the Plutonium Surplus: Applications and Technical Options (ISBN 9780792331247)
OECD NEA 1997, Management of Separated Plutonium, the technical options (ISBN 9264154108)
Nuclear Europe Worldscan, European Nuclear Society, March/April 1997 (several articles)
Nuclear Engineering International, Europeans & MOX , July 1997
D Albright and K Kramer, Tracking Plutonium Inventories, Plutonium Watch, July (revised August) 2005 – see http://www.isis-online.org/global_stocks/end2003/plutonium_watch2005.pdf
International Atomic Energy Agency, Status and Advances in MOX Fuel Technology, Technical Review Series # 415 (2003)
www.moxproject.com, the website for the Mixed Oxide Fuel Fabrication Facility (MFFF) at the Savannah River Site
Marc Arslan, 2012, Fuel Cycle Strategies to Optimise the use of MOX Fuels, WNFC Helsinki.
Related information pages
The Nuclear Fuel Cycle
Processing of Used Nuclear Fuel
Military Warheads as a Source of Nuclear Fuel
Japanese Waste and MOX Shipments From Europe